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Tin Selenide Thin Films Prepared Through Combination of Chemical Precipitation and Vacuum Evaporation Technique

Z. Zainal ¹, S. Nagalingam ¹, A. Kassim ¹, M.Z. Hussein ¹, W.M.M. Yunus ^2
1Department of Chemistry, University Putra Malaysia, Selangor, Malaysia
²Department of Physics, University Putra Malaysia, Selangor, Malaysia

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New Trends in the Investigations of Macrocyclic Magnets

J. Mroziński¹, A. Tomkiewicz¹, M. Nahorska¹, A. Skorupa¹, B. Korybut-Daszkiewicz^2
1Faculty of Chemistry, University of Wrocław, Poland
²Institute of Organic Chemistry, Polish Academy of Sciences, Warszawa, Poland

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Thiolato-bridged Copper Complexes with N,N,S-tridentate Ligands

T. Kotera¹, A. Fujita¹, M. Mikuriya¹, M. Handa^2
1Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Japan
²Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Japan

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Structural Effects on Magnetism of Pyridyl Nitroxide Complexes of Ruthenium(II, III) Pivalate Dimers

M. Handa¹, Y. Sayama², M. Mikuriya², I. Hiromitsu¹, K. Kasuga^1
1Department of Material Science, Interdisciplinary Faculty of Science and Engineering, Shimane University, Japan
²Department of Chemistry, School of Science and Technology, Kwansei Gakuin University, Japan

Abstract

The 1:1 reactions in molar ratio of ruthenium(II,III) pivalate dimer and pyridyl nitronyl nitroxide gave chain complexes, [Ru₂(O₂CCMe₃)₄(L)]_n(BF₄)_n, L = 2-(4-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-N-oxide and 2-(3-pyridyl)-4,4,5,5-tetramethyl-4,5-dihydro-1H-imidazolyl-1-oxyl-3-N-oxide. For the complex with the former radical, the chain structure made up by an alternated dimer-radical arrangement due to the axial coordination of pyridyl nitrogen and one of two nitroxide oxygens of the radical was confirmed by the X-ray diffraction method. Their magnetic behaviors were analyzed by considering magnetic interactions between Ru(II,III) dimer and radical through pyridyl and N-O groups, respectively.

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Metal Complexes Immobilised In/On Porous Matrices - Possible Enzyme Mimics

I. Labádi¹, I. Szilágyi¹, N.I. Jakab², K. Hernádi³, I. Pálinkó^2
1Department of Inorganic and Analytical Chemistry, University of Szeged, Hungary
²Department of Organic Chemistry, University of Szeged, Hungary
³Department of Applied and Environmental Chemistry, University of Szeged, Hungary

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Intramolecular Electron Transfer on the Vibrational Timescale in Mixed Valence Ruthenium Clusters

N. Imai, T. Hamaguchi, T. Yamaguchi, T. Ito
Department of Chemistry, Graduate School of Science, Tohoku University, Sendai, Japan

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Copper(I) Complexes as Potential CVD Precursors - Studies in the Liquid State and Gas Phase

I. Szymańska, R. Kucharek, E. Szłyk
Department of Chemistry, Nicolaus Copernicus University, Toruń, Poland

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Spin Crossover in a Supramolecular FeII-FeIII System

H. Ohta¹, Y. Sunatsuki¹, Y. Ikuta², N. Matsumoto², S. Iijima³, H. Akashi⁴, T. Kambe⁵, M. Kojima1
¹Department of Chemistry, Faculty of Science, Okayama University,Tsushima, Japan
²Department of Chemistry, Faculty of Science, Kumamoto University, Japan
³National Institute of Advanced Industrial Science and Technology, Japan
⁴Research Institute of Natural Sciences, Okayama University of Science, Ridai-cho, Japan
⁵Department of Physics, Faculty of Science, Okayama University, Tsushima, Japan

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Spin-entropy Driven Charge Transfer Phase Transition in Iron Mixed-Valence System

N. Kojima, M. Itoi, Y. Ono, M. Okubo, M. Enmoto
Graduate School of Arts and Sciences, The University of Tokyo, Japan

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Zeta Potential and Doping in Polyaniline Dispersions

D.W.O. de Medeiros¹, D.S. dos Santos², T.N.C. Dantas¹, M.R. Pereira¹, A. Giacometti³, J.L.C. Fonseca^1
1Departamento de Química Universidade Federal do Rio Grande do Norte Lagoa Nova, Natal, Brazil
²Grupo de Polímeros ,,Prof. Bernhard Gross''Instituto de Física de Sao Carlos, Universidade de Sao Paulo, Brazil
³Faculdade de Ciencias e Tecnologia de Presidente Prudente Universidade Estadual Paulista, Brazil

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The Study of the Spin Transition Process in Na[Fe(Th-Sa)₂] by Electron Paramagnetic Resonance

Yu.V. Yablokov¹, V.V. Zelentsov², M. Augustyniak-Jabłokow¹, A. Krupska¹, J. Mroziński^3
1Institute of Molecular Physics PAS, Poznań, Poland
²Moscow Physical Technical Institute, Russia
³Faculty of Chemistry University of Wrocław, Poland

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